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Cement‐SnSe Thermoelectric Devices With High Seebeck Coefficients

GERAINT HOWELLS, Shahin Mehraban, Tom Dunlop Orcid Logo, Nicholas Lavery Orcid Logo, Matt Carnie Orcid Logo, Matthew Burton Orcid Logo

Advanced Electronic Materials, Volume: 12, Issue: 2, Start page: e00649

Swansea University Authors: GERAINT HOWELLS, Shahin Mehraban, Tom Dunlop Orcid Logo, Nicholas Lavery Orcid Logo, Matt Carnie Orcid Logo

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DOI (Published version): 10.1002/aelm.202500649

Abstract

In this work, we present a cost‐effective, scalable approach for fabricating thermoelectric (TE) generators using p‐type tin selenide (SnSe) bonded in a cement matrix via a slurry mold casting technique. Traditional methods for manufacturing SnSe‐based TE materials are energy‐intensive and economica...

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Published in: Advanced Electronic Materials
ISSN: 2199-160X
Published: 2026
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URI: https://cronfa.swan.ac.uk/Record/cronfa71313
Abstract: In this work, we present a cost‐effective, scalable approach for fabricating thermoelectric (TE) generators using p‐type tin selenide (SnSe) bonded in a cement matrix via a slurry mold casting technique. Traditional methods for manufacturing SnSe‐based TE materials are energy‐intensive and economically unfeasible. By contrast, our approach employs common Portland cement as a binder, offering a viable alternative that reduces processing time, complexity, and cost. Ball‐milled SnSe is mixed with varying concentrations of cement and cast into molds for samples, resulting in dimensions of 1.5 × 1.5 × 0.75 cm3. The best‐performing formulations are 0.2 wt.% cement, which exhibited a power factor of 77 µW m−1·K−2 at 800 K and the 0.3 wt.% cement sample, which has a peak ZT of 0.3 at 850 K, the highest ZT of any cement containing TE to date. A proof‐of‐concept thermoelectric generator (TEG) comprising six legs of SnSe‐cement composite demonstrated a peak power output of ∼73 µW at 850 K. Furthermore, calculations show that using the cement‐bonded SnSe to harvest industrial waste heat in a steel‐making environment can yield a potential 1521.3 W m−2 of electrical energy.
Keywords: cement; SnSe; thermoelectrics; tin selenide
College: Faculty of Science and Engineering
Funders: European Regional Development Fund Grant: c80892; Engineering and Physical Sciences Research Council Grant: EP/N020863/1, EP/S018107/1, EP/L015099/1, EP/M028267/1
Issue: 2
Start Page: e00649